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Staying cool without refrigerants: Next-generation Peltier cooling

fghorow

For those worried about tiny COPs from these gizmos, trawling through the actual paper -- as well as the PR from JHU APL -- in this HN post [1] shows claims of COPs of ~15 for Delta Ts of 1.3°C.

A compressor based cooler gets a COP of about 4 in the real world. I'm pretty sure this is an apples to oranges comparison to an expert (I am not one of those) but a factor of 3+ increase in COP is fairly noteworthy -- if it holds up.

[1] https://news.ycombinator.com/item?id=44424087

rcxdude

ugh, reading the paper, their methodology is kinda crap. They basically just guess what the thermal resistances in their system are, and use air temperature measurements to figure out the heat flow. This is not how to measure heat flow accurately. It might be OK as a comparison with whatever TEC they tested with, maybe, but it's not at all something I would trust to compare to another test setup. If their box is more insulative than they think it is, their results are gonna look better than reality. This can be validated at least approximately by just putting a heater in the box that's dissipating a known amount of heat and looking at the temperature rise, but it seems they didn't even do this. And in general the regime where you've got small temperature differences is where your systematic error in a system like this can become huge and distort the results by multiples.

(This is an area which is really hard and details matter. Heat is basically impossible to measure directly, and the indirect measurements are fraught with peril. Getting it wrong was a large part of why people thought they had demonstrated cold fusion)

binarymax

For anyone wondering (like me) what COP is in this context, it’s Coefficient of Performance: https://en.m.wikipedia.org/wiki/Coefficient_of_performance

MobiusHorizons

I believe the “apples to oranges” is the temperature gradient. AC units would routinely manage 15-20c and are rated for more than that. And some freezers manage up to 50c. The greater the gradient the worse the efficiency in general.

mousethatroared

COP has to be compared at the same delta T. The COP of a loss less refrigerator is infinite at Delta T = 0

And you dont get to stack Peltiers to increase COP, only to increase delta T.

Still, Peltiers are super cool and I have some ideas for their use od they get slightly better. Advances are super welcome.

positron26

One can only hope some kind of phonon diode material can exist that a slight voltage can overcome something so inescapable as entropy by providing it only lanes that suit us.

jfengel

The idea was just so astonishing that I ordered some from American Science and Surplus. I connected the leads to a battery and poof, one side got hot and the other got cold. Blew my mind.

I didn't actually have a use for it. It was just neat that it actually worked.

I understand the basic physics of it perfectly well. It's just one of those things where you expect basic physics to be overwhelmed by friction or something.

HPsquared

What about a ΔT of say 20°C? I'd reckon most refrigerators and air conditioners are around there (temp difference of refrigerant between evaporator and condenser).

Stacking a bunch of these Peltiers to give more temperature difference would give a pretty low CoP. Say, for a 13°C temperature difference you'd have to stack 10 of them and use 10x the power. It's even worse actually as the hotter ones have to also pump the waste heat from the cooler ones.

lucb1e

Note that a small temperature difference that is sustained very consistently over a long time using a tiny amount of electricity (let's say half of what the parent post cited, so like a COP of 8) could add up to a lot of nearly-free cooling. You'd chill your walls for weeks and when a heat wave comes with hot nights for a week, if you(r home automation) close(s) the blinds during the heat of the day, the more-powerful AC might barely have to do anything

Just an idea of course, but I'd not write new tech off as "ok but just 1.3 degrees who cares" when the claimed COP is so insanely good without first trying it out

sokoloff

The ΔT between evaporator (typically 2-6°C while cooling) and condenser (often 40-50°C in cooling mode) is much higher than 20°C. The condenser is often almost 20°C above ambient outside temperature.

The design ΔT of ~10°C is the typical return-to-supply air ΔT.

icehawk

The COP generally varies with Delta-T, a compressor-based heat pump's isn't any different. An AC unit is more efficient when it is cooler outside.

That said, 1.5C is tiny.

userbinator

Delta Ts of 1.3°C.

Might as well not use a refrigerator if your ambient temperature is that low.

LeifCarrotson

You missed the "delta", meaning change.

One side would have been ~23C and the other 24.3C.

zdragnar

That's still a lot hotter than I'd like my refrigerator, to be fair to OP.

madaxe_again

The delta of 1.3C is critical there - peltier cooling drops precipitously in efficiency as the delta increases, and struggles to hit a COP of even 1 in real world scenarios. Their figure works out at about 6.5% Carnot efficiency, whereas a normal heat pump is usually nearer 45% over a much broader range of temperatures, as you can separate the hot and cold sides completely. Not so with a peltier wafer.

What they’ve done here is add a point of failure, use additional materials as well as a traditional heat pump, and called it “AI” and “eco friendly”.

Never have I seen more prime VC bait.

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teamonkey

The Johns Hopkins press release is much better

https://www.jhuapl.edu/news/news-releases/250521-apl-thermoe...

tootie

Oh nifty. These can also be used to generate electricity from body heat. Or presumably any waste heat.

dotancohen

Only if you have a cold environment into which to dump that heat into. You could maybe trickle charge your phone in the winter, if you don't mind a cold spot where the device sits on your body.

anticensor

Did they solve the inefficiency problem of peltiers?

bluGill

They claim 75% better. I doubt this is better than compressors in general but they seem to be going for a niche where a high power compressor does the high load part but when only a litte cooling is needed the compressor is now very inefficient and so the peltier is better. Normal fridges just let the temperature have a wider swing which is good enough for most needs.

mort96

> Normal fridges just let the temperature have a wider swing which is good enough for most needs.

These wide swings annoy me. You hear that you shouldn't let your fridge go above 4°C, because that's dangerous. And you obviously don't want your fridge to go below 0°C. But finding a setting where the hottest part of the fridge doesn't go above 4°C (or even 5°C or 6°C) during the hottest part of the cycle and the coldest part of the fridge doesn't go near 0°C during the coldest part of the cycle is really pretty difficult, in my experience.

elzbardico

The time it stays above 4C unless you're opening the door of your refrigerator all the fucking time is mostly negligible in terms of the difference it will make for bacterial growth.

The foodstuff itself is loaded with water, it won't have an excursion dangerously above 4C just because you opened the door and the air temperature raised a few degrees.

If you are really worried about it (you shouldn't), and you don't keep your refrigerator full, add a few water bottles for thermal mass.

nandomrumber

Put a thermometer in a plastic bag (to keep it dry) in a jar of water in your fridge, you'll likely find the temperature of items inside the fridge much more stable than the air temperature.

obfuscator

Why should that be dangerous? I have never heard that.

I have always had my fridge at 8°C and never had something dangerous happen to me. I have never come across fridges that were way cooler, apart from fridges of friends in Canada and the US. What's the reasoning?

javiramos

You should buy a fridge with a fan in the cooling chamber. My Samsung fridge has a nice fan and associated ducting to circulate air and keep temperatures ~uniform.

dangus

If you buy something good like a Sub-Zero it will stay within 1 degree of the set point.

palata

> You hear that you shouldn't let your fridge go above 4°C

Really? My fridge says 8°C, I think?

ethan_smith

Traditional Peltier devices operate at ~10% efficiency (COP of 0.5-0.7) compared to vapor-compression systems (COP of 2-4), but recent advances in thermoelectric materials like bismuth telluride alloys and segmented elements have pushed lab efficiencies to ~15-20%.

HPsquared

It's clearer to think in terms of "efficiency relative to ideal Carnot efficiency".

Compressor systems use twice as much energy as an ideal system, while Peltier systems use about 10x as much.

cosmotic

The article says they have made peltiers 75% more efficient than existing ones.

nine_k

OK, a typical Peltier device has 3.5% coefficient of performance, that is, it produces 35 W of cooling per 1 kW consumed.

Fine, let's expect that the new tech doubles the efficiency, to 7%. Still, to my mind, pretty wasteful, on par with a steam railway engine. A Peltier element is good in cases where you can afford a large heat removal device, but need precise temperature control and no moving parts. For a home fridge, I'll take the sound of the compressor and the temperature fluctuations of a 400% efficient compressor-based heat pump over a Peltier element any day.

sunshine-o

While Peltier cooling have low efficiency wouldn't it be ideal in some cases like:

- energy source is solar, DC already and abundant.

- cold climate so the fridge can contribute to heating the room

Anyway good to know those small electric cooler with Peltier effect must be consuming a lot electricity.

stephen_g

That is wrong, COP is expressed as a ratio, not a percentage (efficiency is expressed as a percentage, which is COP * 100). And as others have said, both efficiency and COP are dependent on ΔT both in refrigeration and thermoelectric cooling.

mousethatroared

"that is, it produces 35 W of cooling per 1 kW consumed."

No, they don't. First, without defining a delta T, efficiency is meaningless (unless its a Carnot cycle).

Second, the efficiency is (depending on op. point) higher than 100%. See [1]. You can pump 20 W of thermal power with 2 A @ 4 V = 8 W

20 W of cooling for 8 W of work, or an efficiency of > 200%. This is common to all refrigeration cycles, and frankly for a puny 10C, it sucks.

[1] https://www.datasheethub.com/wp-content/uploads/2022/10/data...

bluGill

A steam railway engine is a lot better than you would think. They were more efficient than diesel engines when diesel took over - the diesel engine needs much less human labor and so was cheaper overall, but for efficiency steam was better. (Note that diesel technology has improved since the 1950s, so I don't know how they compare now)

Tistron

What I want is a silent refrigerator, will this bring that? pray

refurb

They already exist! Well, small ones.

A hotel I was staying at had a small bar fridge that used a Peltier. I only know because it stopped working so I checked it and realized it was only a Peltier plus a heat exchanged (a cyclopropane loop).

I presume a full size fridge is outside of reach at this point.

bob1029

I've been thinking about what it would look like to convert my GE fridge into a minisplit (i.e., move the compressor, condensing coil & fan outside).

You can buy R600a on Amazon right now. One $60 can will charge the system ~5 times.

theluketaylor

With home HVAC, fridges, water heaters, and dryers all using now able to use of dependent on heat pumps I wonder how long it be before we see modular appliances that connect to coolant lines where the temperature differential is supplied by a central high efficiency heat pump.

Cars already have heat scavenging that can move heat from where it's being created through losses to places where it's valuable, like the cabin or battery pre-heating. Especially in cold climates it feels like homes should be next.

briHass

There's some commercial options for this, but it's not common. Usually, these devices just have their own compressors, because they all pale in comparison to the heat pump(s) used for climate control. For example, I have a HP water heater, and its heat pump is about 1/3 of a ton, whereas most homes need 3+ tons for climate control. Fridges are a fraction of that.

For HP clothes dryers, there's no efficiency to steal from somewhere else, because they use both the hot and cold coils - similar to (the same, really) dehumidifiers.

The tradeoff would also be running high-pressure refrigerant lines everywhere. That would require EPA certification (in the US, anyway) to connect/disconnect an appliance, and it would probably be less reliable. These sealed-system units are generally pretty reliable, because the refrigerant is installed at the factory under ideal conditions, and there's no connections that are made later that may be done poorly.

tasty_freeze

That is an interesting thought, but I assume that the working ranges of the different appliances are different so there would be some complexities and inefficiencies getting them all connected to a common circulation loop. If there was a thermal equivalent of a transformer used for alternating current, that would be amazing.

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userbinator

It's worth noting that the very earliest electric refrigerators had a separate condensing unit outside; see this interesting 1920s Frigidaire training video for an example of what that was like: https://www.youtube.com/watch?v=W-t7DqOAMME

There were also centralised systems for apartments where one condensing unit supplied many evaporators in the refrigerator in each suite.

athenot

My wine fridge uses Peltier and is super quiet. It's the perfect application for this because wine doesn't need to be as cold as a normal fridge, and noise is a consideration.

It's not completely silent though, there's a small PC-like fan but it's way less loud than a compressor.

userbinator

Absorption refrigerators have been around for approximately a century, are silent, and a little more efficient than peltiers.

esseph

You can hear your refrigerator???

bob1029

The latest wave of appliances is really fucking loud for some reason.

I think they're using different kinds of motor windings, bearings, insulation, etc. it's not related to the refrigerant or other system parameters. I've had older r600a fridges that were dead silent compared to anything sitting in a Best Buy showroom right now.

userbinator

Likely high speed compressors --- the oldest hermetic systems used an induction motor running at 1800 RPM, then later they went to 3600 RPM, and now they're running on a VFD that possibly goes much faster. By making it pump faster, they can use a smaller compressor and reduce costs, at the expense of longevity and noise.

madaxe_again

They use lighter lubricant oils than were historically used, which allows more vibration. It’s also why compressors burn out far more quickly than they used to.

frosted-flakes

You can't? Refrigerators have always made a noticeable background noise as they cycle on and off.

The advantage of the newer variable speed scroll compressors in some high end fridges is that they can run continuously at a slower speed.

esseph

In an "open home" concept I guess it might make sense, but I've never lived in a place like that.

I guess all of the places I've lived the kitchen was always its own room, maybe adjacent to the dining room if anything.

No new appliances (>10y now I think about it, they came with the house.)

JoshTriplett

Yes, absolutely. In particular, I find this obnoxious when staying in hotel rooms that have a minifridge.

elzbardico

Move it outside a cabinet, let it free stand. I found out that my nice kitchen niche for the refrigerator acted like a nice resonance chamber for the frequencies the compressor generated.

I can barely hear it now.

Sharlin

If the cabinet is poorly designed (or ventilation is otherwise obstructed), it will also retain heat, making the fridge have to work harder.

NuclearPM

Why?

iLoveOncall

Not OP but it's a massive nuisance if you live in a studio. People don't realize how noisy a fridge is until there's one in the room that they sleep in.

majormajor

New appliances are far better than old ones here. Especially old ones that (I assume) haven't been maintained and so are working far harder than they used to. I've lived in places with old ones that were fine and old ones that were awful, both. I've had much more consistently good results in places with newer ones.

tormeh

Skill issue on the manufacturer's part. I live in a studio and never hear the fridge. This is part of a fitted kitchen, though, but I doubt the panel hiding the fridge makes that big of a difference.

storus

Just today I ordered a 32dB Liebherr; the previous one had 35dB and could be heard all around the studio (I measured the noise using a dedicated sound meter).

42lux

Killed an AMD K6 with my diy peltier cooler when I was 14 good times.

Havoc

Sounds like they’re using much thinner and thus more efficient bonding on each end of the Peltier device?

75% gains off that seems impressive. Must be something really fancy - thinking of a heat sink just using better therm paste barely moves the needle

iLoveOncall

The most impressive thing about this article is that they somehow managed to shoehorn AI in a fridge.

throwawayoldie

Reminiscent of the Long Island Blockchain Company (makers of Long Island Iced Tea (TM)).

throwaway81523

I thought Peltiers can't lower the temperature by more than 40 degrees F, in practice less than that. This is not cold enough for a refrigerator on a warm day.

szvsw

FWIW, in a typical apartment or single-family home, refrigeration uses a fraction of the energy that space cooling (also via a refrigeration/vapor compression cycle) requires on a warm day (and probably year round too unless in very mild climates). The psychrometric chart path is different so there are of course differences in the amount of energy required for the sensible and latent components, but the real difference is just the volume of air that needs to be dealt with.

My point being that at least from an energy and carbon perspective, lowering the space cooling demand via more effective building envelopes or increasing the space cooling supply efficiency - eg via membrane or dessicant dehumidification, better heat pumps etc) is far more impactful on a macro scale than better refrigeration.

Granted refrigeration in a warehouse eg is really also space cooling, but I’m just making the distinction between the dT=0-25F context and the dT>25F context. If I could only choose one technology to arrive at scale to improve the efficiency, it would be for the former context.

closewith

Definitely not the volume of air. The thermal mass of air is tiny.

The difference is in the thermal mass of the building and the surface area exposed to the sun.

rcxdude

Also the area that needs insulating, and in the extremes the amount of air that needs to be exchanged with the outside to make the house livable, and the heat generated by the people living in it (stick a 100W lightbulb in a fridge and see how cold it can get).

The insulation is actually solvable, and for heating can basically remove the power requirements: a house heated and using heat exchange on air leaving vs entering can be heated a lot just by having people inside it, let alone the other energy they use for other purposes. It's just more expensive to build this way, and with cheap energy it can a long time to pay back. Cooling you can't push down past the heat generated inside the house divided by the COP of your cooler, though.

szvsw

Sure I was playing a little fast and loose there, but (a) the large surface area of the home (and resulting conductive transfer through the walls + convection transfer via infiltration through gaps) is directly a result of the fact that you need a significantly larger volume for humans to move around in and live in than you do to store food and (b) even if we do look directly at the volume of air, the difference is significant since at the end of the day, since for any given constant deltaT, your energy spent is still linear with mass or volume. And we are talking about roughly 2-3 orders of magnitude difference in air volume between a house and a refrigerator.

Anyways, if you write out all of the heat balance equations, you get a few W/m2 of flux on the inside wall of the home and a few W/m2 of flux on the inside faces of the fridge, assuming a typical wood frame construction in summer time and steady states all around.

So yes, of course multiplying the flux through the home’s wall by the surface area of the home results in a massive heat gain value compared to the heat gain conducted through the surface of the refrigerator, but that’s arguably precisely because of the two different volume requirements.

mousethatroared

That's a question of mass and power.

numpad0

There are no inherent max temperature deltas for Peltiers, just coefficient of performance, or watts moved per watts wasted, is atrociously low compared to just about everything else.

wtallis

Peltier coolers have non-zero thermal conductivity and are pretty thin. At some point, heat leakage from the hot side to the cool side catches up to the rate of heat removal the cooler is capable of. What that point is will vary between devices, so there's no single or fundamental limit.

rcxdude

You can also stack them, but you need ever-increasing areas of TEC and corresponding power consumption. I think a triple-stack is sometimes practical if you want to get something to well below ambient and it doesn't really generate much heat itself (and you don't really want to use a traditional cooler due to size or vibration or something similar)

BearOso

AI has literally nothing to do with this. Why do they feel the need to sprinkle the phrase everywhere? AI inverter/compressor? Come on, have some sense of shame, please.

rcxdude

It's the name of the game, alas. In the area I work in, I've seen many companies get many multiples of the investment we've gotten because it's "quantum", even though they're trying to do the same thing we're doing and doing less well at it.

throwawayoldie

I assume that if you have "quantum AI", VCs break into your house and force bags of money on you.

savrajsingh

Because it works wonders on non-technical people

dayjah

I worked on a scientific instrument a while ago, it had a Peltier heater on it to raise the sample to 60c from whatever residual environment temp was (approx. 20c in a lab). It was pretty amazing to see my old overclocking cooling solution come back around and be used in my professional career some 20+ years later

madaxe_again

And they couldn’t use a 100% efficient resistive element because…?

rcxdude

The TEC is more than 100% 'efficient' - you get more heat out than power you put in. Though I would guess it's mainly there to get heat control that can span above, around, and slightly below ambient.

mousethatroared

Because Peltiers are, at their most inefficient 100% efficient?

At a reasonable delta T you can get 200% efficiencies.

s0rce

typically only used if you need to stabilize the temp very close to room temperature or cool it below, unusual choice otherwise compared to a heater.

gclawes

I wonder if this will eventually lead to battery temperature conditioning on cell phones and laptops similar to electric cars.

mecsred

Not likely without other contributing technologies. These devices just move heat from one side to the other, at the cost of producing more heat. So you still have to dissipate even more heat on the hot end with a fan/heatsink, in addition to draining the battery running the Peltier.

acgh213

being colorblind, specifically deuteranomaly, it worked, but i do not see the blue green, i see the weird off green i normally do and then basically brown. i would imagine complete red-green would actually impact it